Firefox uses sessionstore.js file in the profile folder to store session data, but this file is only present when Firefox is closed. The sessionstore.js file is created from recovery.js when you close Firefox and is removed and copied to previous.js when you start Firefox to make is possible to restore the session at any time.

You can backup the session files in the sessionstore-backups folder in the Firefox Profile Folder to make sure not to lose possible important session data. You can find these files in the sessionstore-backups folder:

previous.js (cleanBackup: copy of sessionstore.js from previous session that was loaded successfully)
recovery.js (latest version of the sessionstore written during runtime)
recovery.bak (previous version of the sessionstore written during runtime)
upgrade.js-<build_id> (backup created during an upgrade of Firefox)

You can copy a file from the sessionstore-backups folder to the main profile and rename the file to sessionstore.js to replace the current file (make a backup copy of the current sessionstore.js).

See also: http://www.ghacks.net/2014/06/27/mozilla-launches-improved-session-restore-firefox-33/

You can use this button to go to the current Firefox profile folder:

• Help > Troubleshooting Information > Profile Directory: Show Folder (Linux: Open Directory; Mac: Show in Finder)
• http://kb.mozillazine.org/Profile_folder_-_Firefox

I failed to pay attention to detail earlier...

Instead of putting the renamed file into the main profile folder I kept trying to get it to work by placing it in the "sessionstore-backup" folder.

Problem is solved, thanks